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• W2169382203 startingPage "5039" @default.
• W2169382203 abstract "[cis-Ru(II)(dmp)2(H2O)2]2+ (dmp = 2,9-dimethylphenanthroline) was found to be a selective oxidation catalyst using hydrogen peroxide as oxidant. Thus, primary alkenes were very efficiently oxidized via direct carbon−carbon bond cleavage to the corresponding aldehydes as an alternative to ozonolysis. Secondary alkenes were much less reactive, leading to regioselective oxidation of substrates such as 4-vinylcyclohexene and 7-methyl-1,6-octadiene at the terminal position. Primary allylic alcohols were chemoselectively oxidized to the corresponding allylic aldehydes, e.g., geraniol to citral." @default.
• W2169382203 created "2016-06-24" @default.
• W2169382203 creator A5023664537 @default.
• W2169382203 creator A5034097419 @default.
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• W2169382203 date "2005-09-28" @default.
• W2169382203 modified "2023-10-12" @default.
• W2169382203 title "Regioselective Alkene Carbon−Carbon Bond Cleavage to Aldehydes and Chemoselective Alcohol Oxidation of Allylic Alcohols with Hydrogen Peroxide Catalyzed by [<i>cis-</i>Ru(II)(dmp)₂(H₂O)₂]²⁺ (dmp = 2,9-dimethylphenanthroline)" @default.
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• W2169382203 doi "https://doi.org/10.1021/ol052025e" @default.
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