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- W2169388514 endingPage "975" @default.
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- W2169388514 abstract "Tetrathiafulvalenes. XIX. Synthesis and Properties of Electron Conducting Poly-Dithiolene Complexes with Ethylene Tetrathiolat and Tetrathiafulvalene Tetrathiolat as Bridge Ligands [1,3]-Dithiolo[4,5-d]-1,3-dithiol-2,5-dione 7 and 5-(5-oxo[1,3]-dithiolo[4,5–d]1,3-dithiole-2-ylidene)[1,3]-dithiolo[4,5–d]1,3–dithiol-2-one 8 were synthesised from 1,3-dithiole-2-thione-4,5-dithiolat. The ligands react with salts of iron, cobalt, nickel, palladium, platinum and copper to give the polymer complexes 22a–g and 23a–e, respectively. Irradiation of 7 in the presence of iron penta-, dicobalt octa- or nickel tetracarbonyl gives the corresponding dithiolene complexes 21a–c. The amorphous insoluble polymer complexes from types 21, 22, and 23 have been characterised by i.r.-spectroscopy, susceptibility and conductivity measurements. The nickel complexes have the highest electrical conductivity (σRT ∼ 10−1Ω−1cm−1, pellets) with a very low activation energy (0,045 eV, 100–300 K) A high electron delocalization in the direction of the polymer chain and an easy charge transfer from chain to chain is supposed." @default.
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- W2169388514 date "1983-01-01" @default.
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- W2169388514 title "Tetrathiafulvalene. XIX. Synthese und Eigenschaften elektronenleitender Poly-Dithiolenkomplexe mit Ethylentetrathiolat und Tetrathiafulvalentetrathiolat als Brückenliganden" @default.
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- W2169388514 doi "https://doi.org/10.1002/prac.19833250612" @default.
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