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- W2169443034 abstract "Abstract The Hg 0 adsorption and oxidation sites on the CuCl 2 -MF catalyst as well as the role of atomic Cu and Cl in Hg 0 removal were identified by a temperature programmed desorption (TPD) experiment. The reaction mechanism with the participation of O 2 and HCl was investigated. The changes in surface chemistry of fresh, spent and in situ pretreated catalyst with O 2 and/or HCl were investigated by EPR and XPS to better understand the intermediate reaction products and steps. The results suggested that different mercury adsorption sites are existed on the catalyst: Cl adsorption sites and Cu adsorption sites. The binding energy of mercury on the Cu adsorption sites is higher than that on the Cl adsorption sites. O 2 and HCl significantly affected the state of Cu and Cl on the spent catalyst. The interaction between Hg 0 and CuCl 2 with the participation of O 2 and/or HCl follows three steps mechanism: (1) the reduction of CuCl 2 to CuCl for the interaction with Hg 0 , (2) the reoxidation of CuCl for the interaction with O 2 forming an intermediate copper oxygen chloride species, (3) the rechlorination of oxychloride species resulting in the restoration of CuCl 2 . This demonstrated that the interaction between Hg 0 and CuCl 2 is a cycle when O 2 and HCl are contained in the reaction system." @default.
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- W2169443034 date "2016-03-01" @default.
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- W2169443034 title "Removal of elemental mercury from flue gas by recyclable CuCl2 modified magnetospheres catalyst from fly ash. Part 2. Identification of involved reaction mechanism" @default.
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- W2169443034 doi "https://doi.org/10.1016/j.fuel.2015.11.003" @default.
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