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- W2169494236 abstract "Using a simple microscopic model, the kinetic equations of the orientational ordering phase transition are established and the general characters of the kinetic behavior of the first-order and the second-order phase transitions are obtained. The results about the equilibrium state obtained as a special case agree completely with those obtained from the phenomenological theories of the first-order and the second-order phase transitions. The different behavior of these two kinds of phase transitions is explained by a unified model. Meanwhile, the relation between them is given and the possibility of a system transiting from one to another caused by external influence is discussed. Lastly, it is shown that in such a non-equilibrium process, a “potential function” corresponding to the thermodynamic force can be established which is equivalent to the free energy function in the thermodynamics in the equilibrium state and can be used to give the direction and speed of the phase transition in the whole non-equilibrium process too. Avec un simple modèle microscopique, on établis les équations dynamiques de phase-transition en orientation ordre et obtient caractères généraux de comportement dynamique du premier order et deuxième ordre phase-transition. Le résultat sur I'état-equilibre obtenu de lui comme un cas spécial s'accorde complètement avec lequel obtenu par théories phénoménologiques pour phase-transition de l'ordre premier et l'ordre deuxième. Le comportement différent de ces deux genre de phase-transitions est expliqué avec un modèle unifié. En měme temps, la relation entre eux est exprimée, et la possibilité d'un système transitant de l'un à l'autre causé par l'influence extérieure est discutée. En dernier, il est montré que dans un tel processus non-équilibre, une «fonction potentielle» correspondant à la force thermodynamique peut ětre établie iaquelle est equivalent à la fonction-energy-libre en thermo-dynamique dans l'état équilibre mais peut ětre utilisée pour donner la direction et la vitesse de phase-transition dans processus non-équilibre entier." @default.
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- W2169494236 date "1990-03-01" @default.
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- W2169494236 title "The Kinetic Theory of the Orientational Ordering Phase Transition. The Model and the Kinetic Behavior" @default.
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- W2169494236 doi "https://doi.org/10.1002/pssb.2221580112" @default.
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