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• W2169515612 abstract "A series of novel, highly sensitive, and selective azo‐based anion sensors 1–3 have been designed and synthesized from the condensation reaction between 4‐amino azo benzene and three different aldehydes. The structure of the sensors 1–3 were confirmed by IR, HRMS, 1 H NMR, and 13 C NMR spectroscopic methods. Colorimetric naked‐eye analysis revealed the anion detection by receptors 2 and 3 as color changes from yellow to pink and yellow to orange, respectively. Anion sensing ability of all receptors was further investigated by 1 H NMR titration, UV‐vis experiment, and fluorescence titration. UV‐vis measurements highly indicate the selective recognition of fluoride and acetate ions in 9:1 dimethyl sulfoxide–H 2 O (v/v) for receptors 2 and 3. Binding constant value showed among all receptors, receptor 3 has strong affinity toward F − and AcO − in semi‐aqueous medium, which is due to the presence of chromogenic signaling unit in it. The F − ion detection property of receptor 2 in organic medium was also extended in the real sample like toothpaste. Copyright © 2013 John Wiley & Sons, Ltd." @default.
• W2169515612 created "2016-06-24" @default.
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• W2169515612 date "2013-04-18" @default.
• W2169515612 modified "2023-10-16" @default.
• W2169515612 title "Simple azo-based salicylaldimine as colorimetric and fluorescent probe for detecting anions in semi-aqueous medium" @default.
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• W2169515612 doi "https://doi.org/10.1002/jmr.2268" @default.
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