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• W2169563351 abstract "The Raman spectroscopic characterization of the orthorhombic phase of Cs2RuO4 was carried out by means of group theory and quantum chemical analysis. Multiple models based on ruthenate (VI+) tetrahedra were tested, and characterization of all the active Raman modes was achieved. A comparison of Raman spectra of Cs2RuO4, Cs2MoO4, and Cs2WO4 was also performed. Raman laser heating induced a phase transition from an ordered to a disordered structure. The temperature-phase transition was calculated from the anti-Stokes/Stokes ratio and compared with the ones measured at macroscopic scale. The phase transition is connected with tilting and/or rotations of RuO4 tetrahedra, which lead to a disorder at the RuO4 sites. © 2015 The Authors. Journal of Raman Spectroscopy published by John Wiley & Sons Ltd." @default.
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• W2169563351 date "2015-04-28" @default.
• W2169563351 modified "2023-10-08" @default.
• W2169563351 title "Joint Raman spectroscopic and quantum chemical analysis of the vibrational features of Cs₂RuO₄" @default.
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• W2169563351 doi "https://doi.org/10.1002/jrs.4705" @default.
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