Matches in SemOpenAlex for { <https://semopenalex.org/work/W2169651978> ?p ?o ?g. }
- W2169651978 endingPage "101" @default.
- W2169651978 startingPage "97" @default.
- W2169651978 abstract "Two new aromatic organonitrile complexes of pentaamminecobalt(III) have been synthesized, the complexes of 2- and 4-nitrobenzonitrile. The kinetics of their base hydrolysis to coordinated carboxamides have been measured and found to follow a simple second order rate law with rate constants of 180 ± 4 M−1 s−1 and 510 ± 90 M−1 s−1 at 25°C and ionic strength 1.0 for the ortho and para isomers respectively. Rate constants for the hydrolysis of eleven coordinated substituted aromatic nitriles have been found to follow a Hammett type correlation where log k = 1.93σ + 1.30 at 25 °C and ionic strength 1. Carbon-13 NMR studies indicate that the variation in the slope of these Hammett plots for free and coordinated nitrile hydrolysis rates is a transition state effect rather than a ground state phenomenon." @default.
- W2169651978 created "2016-06-24" @default.
- W2169651978 creator A5021329772 @default.
- W2169651978 creator A5051209039 @default.
- W2169651978 creator A5084655643 @default.
- W2169651978 date "1983-01-01" @default.
- W2169651978 modified "2023-10-12" @default.
- W2169651978 title "Reactivity patterns in the base hydrolysis of coordinated aromatic nitriles" @default.
- W2169651978 cites W1573433661 @default.
- W2169651978 cites W1966814641 @default.
- W2169651978 cites W1968153746 @default.
- W2169651978 cites W1969851333 @default.
- W2169651978 cites W1984095641 @default.
- W2169651978 cites W1994596533 @default.
- W2169651978 cites W2003954963 @default.
- W2169651978 cites W2013523789 @default.
- W2169651978 cites W2031074314 @default.
- W2169651978 cites W2040248555 @default.
- W2169651978 cites W2045772609 @default.
- W2169651978 cites W2057126821 @default.
- W2169651978 cites W2057607512 @default.
- W2169651978 cites W2068173160 @default.
- W2169651978 cites W2068490671 @default.
- W2169651978 cites W2068966023 @default.
- W2169651978 cites W2077661562 @default.
- W2169651978 cites W2092162609 @default.
- W2169651978 cites W2318917020 @default.
- W2169651978 cites W2330281130 @default.
- W2169651978 cites W3004950474 @default.
- W2169651978 cites W3138767372 @default.
- W2169651978 cites W3138976218 @default.
- W2169651978 doi "https://doi.org/10.1016/s0020-1693(00)88944-6" @default.
- W2169651978 hasPublicationYear "1983" @default.
- W2169651978 type Work @default.
- W2169651978 sameAs 2169651978 @default.
- W2169651978 citedByCount "17" @default.
- W2169651978 countsByYear W21696519782021 @default.
- W2169651978 crossrefType "journal-article" @default.
- W2169651978 hasAuthorship W2169651978A5021329772 @default.
- W2169651978 hasAuthorship W2169651978A5051209039 @default.
- W2169651978 hasAuthorship W2169651978A5084655643 @default.
- W2169651978 hasConcept C121332964 @default.
- W2169651978 hasConcept C134306372 @default.
- W2169651978 hasConcept C142724271 @default.
- W2169651978 hasConcept C145148216 @default.
- W2169651978 hasConcept C147597530 @default.
- W2169651978 hasConcept C148898269 @default.
- W2169651978 hasConcept C155647269 @default.
- W2169651978 hasConcept C178790620 @default.
- W2169651978 hasConcept C184651966 @default.
- W2169651978 hasConcept C185592680 @default.
- W2169651978 hasConcept C187428577 @default.
- W2169651978 hasConcept C204787440 @default.
- W2169651978 hasConcept C2182769 @default.
- W2169651978 hasConcept C2776910235 @default.
- W2169651978 hasConcept C2779240715 @default.
- W2169651978 hasConcept C33923547 @default.
- W2169651978 hasConcept C42058472 @default.
- W2169651978 hasConcept C62520636 @default.
- W2169651978 hasConcept C71924100 @default.
- W2169651978 hasConcept C93391505 @default.
- W2169651978 hasConcept C94412978 @default.
- W2169651978 hasConceptScore W2169651978C121332964 @default.
- W2169651978 hasConceptScore W2169651978C134306372 @default.
- W2169651978 hasConceptScore W2169651978C142724271 @default.
- W2169651978 hasConceptScore W2169651978C145148216 @default.
- W2169651978 hasConceptScore W2169651978C147597530 @default.
- W2169651978 hasConceptScore W2169651978C148898269 @default.
- W2169651978 hasConceptScore W2169651978C155647269 @default.
- W2169651978 hasConceptScore W2169651978C178790620 @default.
- W2169651978 hasConceptScore W2169651978C184651966 @default.
- W2169651978 hasConceptScore W2169651978C185592680 @default.
- W2169651978 hasConceptScore W2169651978C187428577 @default.
- W2169651978 hasConceptScore W2169651978C204787440 @default.
- W2169651978 hasConceptScore W2169651978C2182769 @default.
- W2169651978 hasConceptScore W2169651978C2776910235 @default.
- W2169651978 hasConceptScore W2169651978C2779240715 @default.
- W2169651978 hasConceptScore W2169651978C33923547 @default.
- W2169651978 hasConceptScore W2169651978C42058472 @default.
- W2169651978 hasConceptScore W2169651978C62520636 @default.
- W2169651978 hasConceptScore W2169651978C71924100 @default.
- W2169651978 hasConceptScore W2169651978C93391505 @default.
- W2169651978 hasConceptScore W2169651978C94412978 @default.
- W2169651978 hasLocation W21696519781 @default.
- W2169651978 hasOpenAccess W2169651978 @default.
- W2169651978 hasPrimaryLocation W21696519781 @default.
- W2169651978 hasRelatedWork W1594920453 @default.
- W2169651978 hasRelatedWork W2049218890 @default.
- W2169651978 hasRelatedWork W2085137194 @default.
- W2169651978 hasRelatedWork W2148543804 @default.
- W2169651978 hasRelatedWork W2159009597 @default.
- W2169651978 hasRelatedWork W2949696832 @default.
- W2169651978 hasRelatedWork W2952226076 @default.
- W2169651978 hasRelatedWork W2953284066 @default.
- W2169651978 hasRelatedWork W4226027378 @default.
- W2169651978 hasRelatedWork W4292442895 @default.
- W2169651978 hasVolume "68" @default.
- W2169651978 isParatext "false" @default.