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- W2169663323 abstract "The poly(methyl acrylate) (PMA) and poly(methyl acrylate-co-sodium methacrylate) containing 6.9 mol% of ionic groups (PMANa-6.9) were studied by 13C CP/MAS NMR. The 13C spin–lattice relaxation times in a rotating frame, T1ρ, have been measured as a function of temperature. Using these T1ρ spin–lattice relaxation times, we discuss the mobility, the correlation time, and activation energy for the PMA and PMANa-6.9, respectively. The molecular motion in the PMANa-6.9 needs higher activation energies than in PMA. It is worth noting that the motion of the 1-methyl carbons in the PMANa-6.9 ionomer distinctly differs from that in the PMA homopolymer. The slow side of the T1ρ minimum associated with the 1-methyl carbons is ascribed to stronger interactions between the polymer chains in the ionomer than in the homopolymer." @default.
- W2169663323 created "2016-06-24" @default.
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- W2169663323 date "2000-06-01" @default.
- W2169663323 modified "2023-09-26" @default.
- W2169663323 title "Poly(methyl acrylate-co-sodium methacrylate) ionomer studied by solid state 13C T1ρ NMR" @default.
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- W2169663323 doi "https://doi.org/10.1016/s0038-1098(00)00164-2" @default.
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