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- W2169667874 abstract "In an effort to use clean technologies, fatty acid methyl esters (FAME) produced from canola have been used as a polymerization solvent. Solution polymerizations of four commercially important monomers have been studied using FAME as a solvent. A series of methyl methacrylate (MMA), styrene (Sty), butyl acrylate (BA) and vinyl acetate (VAc) homopolymerizations in FAME were carried out at 60 °C at different solvent concentrations. Chain transfer to solvent rate constants were obtained using the Mayo method. The transfer constants increased in the order: MMA < Sty < BA < VAc. Under the conditions studied, the MMA solution polymerization in FAME was observed to behave as a precipitation polymerization. The estimated chain transfer to solvent rate constants were employed in a polymerization simulator to predict the polymerization rates and average molecular weights." @default.
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- W2169667874 date "2008-01-01" @default.
- W2169667874 modified "2023-09-23" @default.
- W2169667874 title "Biodiesel: a green polymerization solvent" @default.
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- W2169667874 doi "https://doi.org/10.1039/b715047d" @default.
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