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• W2169672103 endingPage "9014" @default.
• W2169672103 startingPage "9005" @default.
• W2169672103 abstract "Abstract The development of novel Brønsted acids featuring the hexacoordinate phosphorus(V) anion [TRISPHAT] − {[ 1 ] − =[P(1,2‐O 2 C 6 Cl 4 ) 3 ] − } are reported. The title compound, H(OEt 2 ) 2 [ 1 ], was synthesized from 1,2‐(HO) 2 C 6 Cl 4 (3 equiv) and PCl 5 in the presence of diethyl ether. This compound was fully characterized by 1 H, 31 P and 13 C NMR spectroscopy, X‐ray crystallography and elemental microanalysis. Dissolution of H(OEt 2 ) 2 [ 1 ] in acetonitrile results in the slow precipitation of crystalline H(OEt 2 )(NCMe)[ 1 ], which was characterized by X‐ray diffraction; however, in CD 2 Cl 2 solution the [TRISPHAT] − anion protonated and ring‐opened. The weighable, solid H(OEt 2 ) 2 [ 1 ] was found to be a competent initiator for the polymerization of n ‐butyl vinyl ether, α‐methylstyrene, styrene and isoprene at a variety of temperatures and monomer‐to‐initiator ratios. At low temperatures, polymers with M n >10 5 were obtained for n ‐butyl vinyl ether and α‐methylstyrene whereas slightly lower molecular weights were obtained with styrene and isoprene (10 4 < M n <10 5 ). The poly(α‐methylstyrene) synthesized at −78 °C is syndiotactic‐rich (ca. 87 % rr ) whereas the polystyrene obtained at −50 °C is atactic. The polyisoprene obtained possessed all possible modes of enchainment as well as branched and/or cyclic structures that are often observed in polyisoprene." @default.
• W2169672103 created "2016-06-24" @default.
• W2169672103 creator A5010108895 @default.
• W2169672103 creator A5059859613 @default.
• W2169672103 creator A5061768733 @default.
• W2169672103 date "2013-05-15" @default.
• W2169672103 modified "2023-10-18" @default.
• W2169672103 title "H(OEt₂)₂[P(1,2-O₂C₆Cl₄)₃]: Synthesis, Characterization, and Application as a Single-Component Initiator for the Carbocationic Polymerization of Olefins" @default.
• W2169672103 cites W1564475094 @default.
• W2169672103 cites W1588918362 @default.
• W2169672103 cites W1966013541 @default.
• W2169672103 cites W1968535968 @default.
• W2169672103 cites W1969459014 @default.
• W2169672103 cites W1970413718 @default.
• W2169672103 cites W1970599211 @default.
• W2169672103 cites W1971236898 @default.
• W2169672103 cites W1976733398 @default.
• W2169672103 cites W1979094899 @default.
• W2169672103 cites W1980862605 @default.
• W2169672103 cites W1981936908 @default.
• W2169672103 cites W1982047370 @default.
• W2169672103 cites W1986276772 @default.
• W2169672103 cites W1987631262 @default.
• W2169672103 cites W1989621989 @default.
• W2169672103 cites W1989816881 @default.
• W2169672103 cites W1991478525 @default.
• W2169672103 cites W1991521931 @default.
• W2169672103 cites W1994212274 @default.
• W2169672103 cites W1995196643 @default.
• W2169672103 cites W1995442152 @default.
• W2169672103 cites W1996273492 @default.
• W2169672103 cites W1997500493 @default.
• W2169672103 cites W1997630901 @default.
• W2169672103 cites W1999002717 @default.
• W2169672103 cites W2003106491 @default.
• W2169672103 cites W2009726182 @default.
• W2169672103 cites W2011912272 @default.
• W2169672103 cites W2011939065 @default.
• W2169672103 cites W2013468066 @default.
• W2169672103 cites W2015253591 @default.
• W2169672103 cites W2015478441 @default.
• W2169672103 cites W2016749878 @default.
• W2169672103 cites W2016912799 @default.
• W2169672103 cites W2019658253 @default.
• W2169672103 cites W2021578144 @default.
• W2169672103 cites W2021849658 @default.
• W2169672103 cites W2024293369 @default.
• W2169672103 cites W2024697339 @default.
• W2169672103 cites W2025339467 @default.
• W2169672103 cites W2030073891 @default.
• W2169672103 cites W2030841140 @default.
• W2169672103 cites W2036074260 @default.
• W2169672103 cites W2038487738 @default.
• W2169672103 cites W2039170834 @default.
• W2169672103 cites W2039836847 @default.
• W2169672103 cites W2042166261 @default.
• W2169672103 cites W2042368783 @default.
• W2169672103 cites W2042554188 @default.
• W2169672103 cites W2043471783 @default.
• W2169672103 cites W2044626693 @default.
• W2169672103 cites W2046690902 @default.
• W2169672103 cites W2047879317 @default.
• W2169672103 cites W2048695145 @default.
• W2169672103 cites W2050524652 @default.
• W2169672103 cites W2053238537 @default.
• W2169672103 cites W2054521460 @default.
• W2169672103 cites W2056844988 @default.
• W2169672103 cites W2057390396 @default.
• W2169672103 cites W2061670814 @default.
• W2169672103 cites W2063334178 @default.
• W2169672103 cites W2064329628 @default.
• W2169672103 cites W2064581376 @default.
• W2169672103 cites W2064962260 @default.
• W2169672103 cites W2066447587 @default.
• W2169672103 cites W2069656276 @default.
• W2169672103 cites W2074359002 @default.
• W2169672103 cites W2076390604 @default.
• W2169672103 cites W2078303342 @default.
• W2169672103 cites W2080385139 @default.
• W2169672103 cites W2081370066 @default.
• W2169672103 cites W2082441600 @default.
• W2169672103 cites W2082443721 @default.
• W2169672103 cites W2083793125 @default.
• W2169672103 cites W2083924613 @default.
• W2169672103 cites W2084882371 @default.
• W2169672103 cites W2088992890 @default.
• W2169672103 cites W2093188212 @default.
• W2169672103 cites W2094286101 @default.
• W2169672103 cites W2109511767 @default.
• W2169672103 cites W2110267483 @default.
• W2169672103 cites W2115807363 @default.
• W2169672103 cites W2131350133 @default.
• W2169672103 cites W2131612644 @default.
• W2169672103 cites W2133970057 @default.
• W2169672103 cites W2136072701 @default.
• W2169672103 cites W2136168875 @default.
• W2169672103 cites W2139009781 @default.
• W2169672103 cites W2140426227 @default.

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