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- W2169703180 abstract "Copper(II) halides, CuX2 (X = Br−, Cl−), have been combined in non-aqueous medium with various α,-β-dione dioxime (α,β-dodoH) ligands to produce new 1:1 adducts, the di-μ-halo-bis[halo(α,β-dodoH)copper(II)] dimers. These are: Di-μ-bromo-bis[bromo(ethanedialdioxime)copper(II)]; di-μ-bromo-bis[bromo(diphenylethanedione dioxime)copper(II)]; di-μ-bromo-bis-[bromo(9,10phenanthrenedione dioxime)copper(II)]; di-μ-chloro-bis-[chloro(9,10-phenanthrenedione dioxime)copper(II)]. The materials were characterized by conventional methods. The results clearly indicate that the compounds crystallize in discrete dimers, quite consistent with the results of closely related dimers studied earlier. Superaustausch in Kupfer(II)-Dimeren. 3. Synthese und Charakterisierung von binuklearen Addukten von Kupfer(II)-Halogeniden mit einigen α,β-Diondioximen Kupfer(II)-Halogenide, CuX2 (X = Br−, Cl−) wurden in nichtwäßrigem Medium mit verschiedenen α,β-Diondioxim (α,β-dodoH)-Liganden zu folgenden neuen 1:1-Addukten, den Di-μ-halo-bis[halo(α,β-dodoH)kupfer(II)]-Dimeren, vereinigt: Di-μ-bromo-bis[bromo(ethandialdioxim)kupfer(II)]; Di-μ-bromo-bis[bromo(diphenylethandiondioxim)kupfer(II)]; Di-μ-bromo-bis[bromo(9,10-phenanthrendiondioxim)kupfer(II)]; Di-μ-chloro-bis[chloro(9,10-phenanthrendiondioxim)kupfer(II)]. Die Substanzen wurden nach konventionellen Methoden charakterisiert. Die Ergebnisse zeigen deutlich, daß diese Verbindungen in getrennten Dimeren kristallisieren, ganz in Übereinstimmung mit früheren Ergebnissen an nahe verwandten Dimeren." @default.
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- W2169703180 date "1982-01-01" @default.
- W2169703180 modified "2023-09-27" @default.
- W2169703180 title "Superexchange in copper(II) Dimers. 3. Synthesis and characterization of binuclear adducts of copper(II) halides with some ?,?-dione dioximes" @default.
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- W2169703180 doi "https://doi.org/10.1002/zaac.19824840119" @default.
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