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- W2169708356 abstract "The new compound tetrakis(phenylmethoxy)methane (also known as benzyl orthocarbonate) has been produced by the action of the sodium salt of benzyl alcohol on trichloronitromethane (chloropicrin), resulting in a white crystalline solid with a melting range of 68–70 °C. The crystal structure has been determined at 153(5) K: triclinic, [Formula: see text], a = 10.161(4) Å, b = 12.664(4) Å, c = 20.472(5) Å, α = 71.78(2)°, β = 82.30(3)°, γ = 71.92(2)°. The results show the symmetry at each central carbon to be approximately S 4 , with average C—O bond lengths of 1.397(4) Å, O—C—O angles ranging between 113–114° and 107–108°, and C—O—C angles of 115(1)°. Additional evidence for this structure is given by nuclear magnetic resonance, infrared and mass spectra. Keywords: benzyl orthocarbonate, orthocarbonate, tetrakis(phenylmethoxy)methane." @default.
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- W2169708356 date "1989-01-01" @default.
- W2169708356 modified "2023-10-17" @default.
- W2169708356 title "The preparation and crystal structure of tetrakis(phenylmethoxy)methane" @default.
- W2169708356 doi "https://doi.org/10.1139/v89-024" @default.
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