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- W2169742666 abstract "Summary: Poly(vinyl acetate) macroinitiators end-capped by a Co(acac)2 complex (PVAc–Co(acac)2), prepared in bulk by cobalt-mediated radical polymerization (CMRP), are used for the controlled radical polymerization of vinyl acetate in miniemulsion to give high-molecular-weight polymers and high monomer conversion. Stable poly(vinyl acetate) latexes with solid contents ranging from 25 to 30 wt.-% are prepared within unusually short reaction times (∼1 h) at low temperatures (0–30 °C). SEC chromatograms for the PVAc–Co(acac)2 macroinitiator and PVAc latex obtained under ultrasonication for 6 min at 0 °C (79% monomer conversion)." @default.
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- W2169742666 date "2006-01-03" @default.
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- W2169742666 title "Cobalt-Mediated Radical Polymerization of Vinyl Acetate in Miniemulsion: Very Fast Formation of Stable Poly(vinyl acetate) Latexes at Low Temperature" @default.
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- W2169742666 doi "https://doi.org/10.1002/marc.200500645" @default.
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