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• W2169743009 startingPage "359" @default.
• W2169743009 abstract "Die Allylboronsäureester 3 substituierter Campherglycole 2 wurden mit Acetaldehyd zu 4-Penten-2-ol (1) umgesetzt. Dabei ist die Substituentenwirkung auf die Größe der asymmetrischen Induktion annähernd additiv. Mit 2d als chiralem Hilfsstoff konnte Pentenol von 86% e.e. erhalten werden. Stereoselective Synthesis of Alcohols, VI1) Asymmetric Synthesis of 4-Penten-2-ol via Allylboronates of Chiral Glycols Allylboronates 3 of substituted camphor glycols 2 add to acetaldehyde giving 4-penten-2-ol (1). The substituents affect the extent of asymmetric induction in an additive manner. Pentenol of 86% enantiomeric purity was obtained using 2d as chiral matrix." @default.
• W2169743009 created "2016-06-24" @default.
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• W2169743009 date "1981-01-01" @default.
• W2169743009 modified "2023-10-14" @default.
• W2169743009 title "Stereoselektive Synthese von Alkoholen, VI ¹⁾ Asymmetrische Synthesen von 4‐Penten‐2‐ol über Allylboronsäureester chiraler Glycole" @default.
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• W2169743009 doi "https://doi.org/10.1002/cber.19811140138" @default.
• W2169743009 hasPublicationYear "1981" @default.
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