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- W2169771775 abstract "Using scanning tunnelling microscopy (STM) and x-ray diffraction (XRD), the assembling behaviour of substituted phthalocyanine and porphyrin on both hydrophobic and hydrophilic surfaces was investigated. Copper (II) 2,3,9,10,16,17,23,24-octakis(octyloxy)-29H,31H-phthalocyanine (denoted as CuPcOC8) and 21,23-dihydro-5,10,15,20-tetrakis[4-(tetradecyloxy)phenyl]porphyrin (TTPP) molecules adsorb stably on a highly oriented pyrolytic graphite (HOPG) surface, yielding high-resolution STM images. The results illustrate that alkyl molecular anchors can be used as a generalized approach for immobilization of organic molecules on hydrophobic surfaces. The XRD results show that on a hydrophilic substrate CuPcOC8 and TTPP form completely different assembled structures from those on a HOPG surface, which indicates that the polarity of the substrate has substantial effects on the assembling behaviour of organic molecules. Copyright © 2002 John Wiley & Sons, Ltd." @default.
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- W2169771775 date "2002-01-01" @default.
- W2169771775 modified "2023-09-26" @default.
- W2169771775 title "STM and XRD studies of the adsorption and assembling structures of phthalocyanine and porphyrin" @default.
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- W2169771775 doi "https://doi.org/10.1002/sia.1407" @default.
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