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• W2169797345 abstract "The 1,2,4-trioxolane and 1,2,4,5-tetroxane pharmacophores are currently considered as the next generation of synthetic antimalarial drugs. This fact has stimulated the exploration of the chemiluminescence displayed by these cyclic peroxides in biomimetic reactions with Fe(II). The CL has been induced by FeSO4 and/or the FeCl3/L-cysteine/Rhodamine G system in aqueous (50%) acetonitrile. The light emission in the visible spectral region has been recorded for triterpenoid-based 1,2,4-trioxolanes, purely synthetic ozonide OZ03, bicyclic 1,2,4,5-tetroxanes, a tetroxane derived from deoxycholic acid, the diperoxide of trifluoroacetone, as well as the natural artemisinin. The herein discovered CL provides a promising perspective for the study of pharmacologically active peroxides in biomedical applications." @default.
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• W2169797345 date "2012-01-01" @default.
• W2169797345 modified "2023-10-03" @default.
• W2169797345 title "Chemiluminescence from the biomimetic reaction of 1,2,4-trioxolanes and 1,2,4,5-tetroxanes with ferrous ions" @default.
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• W2169797345 doi "https://doi.org/10.1039/c1ra00784j" @default.
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