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- W2169803886 abstract "The influence of bath pH and also citrate and molybdate concentration, on the electrodeposition process of ternary Zn-Ni-Mo alloy coatings has been examined. The occurrence of the particular forms of the metal-citrate complexes in the electrolytes was analysed using UV-VIS spectroscopy and on the basis of the stability constants of the complexes. In the solutions with lower pH (4·5 and 5·7), in which free metal ions and ZnHCit− and NiHCit− complexes predominate, anomalous codeposition of nickel with zinc took place. In electrolytes with higher pH, containing excess of citrate, in which all the metal ions occur in the form of citrate complexes, and about 20% of the Zn2+ and Ni2+ ions form a ZnNiCit24− mixed complex, the codeposition changes from anomalous to normal. The percentage of Mo in the alloy increases with the increase in concentration of uncomplexed MoO42− ions in the solution. Alloys with much higher Mo content may be obtained from the bath in which preferential deposition of nickel (normal codeposition) takes place." @default.
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- W2169803886 date "2014-07-01" @default.
- W2169803886 modified "2023-10-18" @default.
- W2169803886 title "Influence of bath concentration and pH on electrodeposition process of ternary Zn-Ni-Mo alloy coatings" @default.
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- W2169803886 doi "https://doi.org/10.1179/0020296714z.000000000183" @default.
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