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- W2169849100 endingPage "12261" @default.
- W2169849100 startingPage "12255" @default.
- W2169849100 abstract "Abstract As a result of detailed mechanistic and kinetic studies, we have proposed that PdX 2 ‐catalyzed oxidative coupling of o ‐alkynylanilines 1 with terminal alkynes 2 under aerobic conditions is initiated by aminopalladation of 1 followed by ligand exchange of the resulting σ‐indolylpalladium(II) complex with 2 , reductive elimination and N‐demethylation. Side reactions associated with intermediates on the way to 2,3‐disubstituted indoles 3 were identified, and the roles of acetate and iodide in channeling the reaction towards the desired product were established. Based on kinetic and spectroscopic studies, the soluble iodide‐ligated Pd 0 species was proposed to be the resting state of the catalyst and its oxidation to active Pd II species was the turnover‐limiting step. Catalytic conditions with low loading of Pd(OAc) 2 (0.0005 to 0.001 equiv) were subsequently developed." @default.
- W2169849100 created "2016-06-24" @default.
- W2169849100 creator A5024407258 @default.
- W2169849100 creator A5046225712 @default.
- W2169849100 creator A5055586375 @default.
- W2169849100 date "2014-08-08" @default.
- W2169849100 modified "2023-10-18" @default.
- W2169849100 title "Mechanistic Study on the Palladium(II)-Catalyzed Synthesis of 2,3-Disubstituted Indoles Under Aerobic Conditions: Anion Effects and the Development of a Low-Catalyst-Loading Process" @default.
- W2169849100 cites W1497742988 @default.
- W2169849100 cites W1968570899 @default.
- W2169849100 cites W1970800627 @default.
- W2169849100 cites W1975405006 @default.
- W2169849100 cites W1977759754 @default.
- W2169849100 cites W1978801682 @default.
- W2169849100 cites W1979844089 @default.
- W2169849100 cites W1982996958 @default.
- W2169849100 cites W2001614462 @default.
- W2169849100 cites W2002712098 @default.
- W2169849100 cites W2004174458 @default.
- W2169849100 cites W2012007763 @default.
- W2169849100 cites W2013944689 @default.
- W2169849100 cites W2015117514 @default.
- W2169849100 cites W2018098301 @default.
- W2169849100 cites W2018178584 @default.
- W2169849100 cites W2018514966 @default.
- W2169849100 cites W2020419388 @default.
- W2169849100 cites W2022243633 @default.
- W2169849100 cites W2023994662 @default.
- W2169849100 cites W2025520647 @default.
- W2169849100 cites W2029419737 @default.
- W2169849100 cites W2030453463 @default.
- W2169849100 cites W2031644569 @default.
- W2169849100 cites W2033020343 @default.
- W2169849100 cites W2038808854 @default.
- W2169849100 cites W2044737684 @default.
- W2169849100 cites W2046559834 @default.
- W2169849100 cites W2047876739 @default.
- W2169849100 cites W2048489115 @default.
- W2169849100 cites W2049786401 @default.
- W2169849100 cites W2050408187 @default.
- W2169849100 cites W2054036488 @default.
- W2169849100 cites W2054085419 @default.
- W2169849100 cites W2054785509 @default.
- W2169849100 cites W2058223844 @default.
- W2169849100 cites W2059327616 @default.
- W2169849100 cites W2065651066 @default.
- W2169849100 cites W2067862427 @default.
- W2169849100 cites W2071103795 @default.
- W2169849100 cites W2076882723 @default.
- W2169849100 cites W2077233310 @default.
- W2169849100 cites W2077621718 @default.
- W2169849100 cites W2081728812 @default.
- W2169849100 cites W2084790801 @default.
- W2169849100 cites W2085081277 @default.
- W2169849100 cites W2085105665 @default.
- W2169849100 cites W2085587206 @default.
- W2169849100 cites W2088980727 @default.
- W2169849100 cites W2091498167 @default.
- W2169849100 cites W2092695896 @default.
- W2169849100 cites W2093909077 @default.
- W2169849100 cites W2095280856 @default.
- W2169849100 cites W2098498855 @default.
- W2169849100 cites W2099615748 @default.
- W2169849100 cites W2099777110 @default.
- W2169849100 cites W2105554902 @default.
- W2169849100 cites W2105587301 @default.
- W2169849100 cites W2115124231 @default.
- W2169849100 cites W2116504877 @default.
- W2169849100 cites W2116919923 @default.
- W2169849100 cites W2121573173 @default.
- W2169849100 cites W2124680160 @default.
- W2169849100 cites W2130069956 @default.
- W2169849100 cites W2130986889 @default.
- W2169849100 cites W2133139437 @default.
- W2169849100 cites W2133531584 @default.
- W2169849100 cites W2138517415 @default.
- W2169849100 cites W2141453896 @default.
- W2169849100 cites W2143562550 @default.
- W2169849100 cites W2145328586 @default.
- W2169849100 cites W2148131801 @default.
- W2169849100 cites W2150338396 @default.
- W2169849100 cites W2150638081 @default.
- W2169849100 cites W2150916408 @default.
- W2169849100 cites W2151320294 @default.
- W2169849100 cites W2151649898 @default.
- W2169849100 cites W2151656593 @default.
- W2169849100 cites W2152919588 @default.
- W2169849100 cites W2153138704 @default.
- W2169849100 cites W2153357499 @default.
- W2169849100 cites W2154991106 @default.
- W2169849100 cites W2156391363 @default.
- W2169849100 cites W2156757182 @default.
- W2169849100 cites W2162721076 @default.
- W2169849100 cites W2171292320 @default.
- W2169849100 cites W2171913390 @default.
- W2169849100 cites W2179238744 @default.
- W2169849100 cites W2315329344 @default.
- W2169849100 cites W2315549348 @default.