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- W2169883375 abstract "2-Ethoxycarbonylmethylidine-4,5-dihydro-4-thiazolinone (1) was condensed with bis aromatic aldehydes such as terephthalaldehyde or 4,4′-bisformyl-diphenylether (2a,b) (2:1 molar ratio) and furnished bis-4-thiaozlidinones (3a,b). The reaction of (3a,b) with malononitrile and aromatic aldehydes (1:2:2 molar ratio) gave bis thiazolopyridines (4a–d). Bis-(thiazolopyridine) derivative (6) was obtained by reaction of 4-thiaozlinone (5c) with bis aldehyde (2b) in refluxing ethanol containing piperidine. Cyclization of 4-thiazolinones (5a,b) with different α-cyanocinnamonitriles gave thiazolo[3,2-a]pyridines (7a–d). Compound 9 was produced via the reaction of 8 with thioglycolic acid, which reacted with p-chlorobenzaldehyde to produce 10. Compound 10 was condensed with hydrazine hydrate and afforded 11. Compounds 12 and 16a,b were produced by the reaction of 9 with isatin and α-ethoxycarbonylcinnamonitriles, respectively." @default.
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- W2169883375 date "2010-06-30" @default.
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- W2169883375 title "Some Cyclization Reactions with 2-Ethoxycarbonylmethylidene-4,5-Dihydro-4-Thiazolinone" @default.
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