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• W2169966810 abstract "The isotherms of monomolecular films of monomers of 3-BCMU, 4-BCMU, and 9-BCMU all reveal a phase transition which resembles that of the corresponding polymers. However, the transition exhibited by the 3-BCMU monomer is not well-defined, and the isotherm is somewhat metastable. The isotherms of the monomers of both 4-BCMU and 9-BCMU show a metastable peak at the onset of the transition due to difficulty in achieving the transition from a bipolar (expanded) to a pseudo-monopolar (condensed) attachment to the water interface. Fluorescence microscopy enabled the two-phase region of the transition to be visualized for 4-BCMU and 9-BCMU but not that of 3-BCMU. The resultant micrographs reveal dark regions representing the condensed monomer phase from which the probe is effectively excluded. The condensed phase domains consist of curved leaf or needlelike regions whose precise size and texture depend on both the molecular composition and the rate of compression of the film. It was also observed that the condens..." @default.
• W2169966810 created "2016-06-24" @default.
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• W2169966810 date "1999-08-01" @default.
• W2169966810 modified "2023-09-27" @default.
• W2169966810 title "Interfacial Compression and Polymerization of 4- and 9-((Butoxycarbonyl)methyl)urethane−Diacetylene Monomolecular Films: A Fluorescence Microscopy Study" @default.
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• W2169966810 doi "https://doi.org/10.1021/ma9902549" @default.
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