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- W2170006543 abstract "Abstract The first transition‐metal‐catalyzed cross‐coupling reactions of 2,3,5‐tribromo‐1 H ‐inden‐1‐one are reported. The Suzuki–Miyaura reaction of 2,3,5‐tribromo‐1 H ‐inden‐1‐one with three equivalents of arylboronic acid gave 2,3,5‐triaryl‐1 H ‐inden‐1‐ones. The reaction with one and two equivalents of arylboronic acid gave 2,5‐dibromo‐3‐aryl‐1 H ‐inden‐1‐ones and 5‐bromo‐2,3‐diaryl‐1 H ‐inden‐1‐ones, respectively, with very good site‐selectivity. The one‐pot reaction of 2,3,5‐tribromo‐1 H ‐inden‐1‐one with one equivalent of two different arylboronic acids afforded 5‐bromo‐2,3‐diaryl‐1 H ‐inden‐1‐ones containing two different terminal aryl groups. Other one‐pot reactions allowed the synthesis of 2,3,5‐triaryl‐1 H ‐inden‐1‐ones containing different aryl groups." @default.
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- W2170006543 date "2011-06-01" @default.
- W2170006543 modified "2023-09-26" @default.
- W2170006543 title "Site-Selective Synthesis of Arylated Indenones by Suzuki-Miyaura Cross-Coupling Reactions of 2,3,5-Tribromoinden-1-one" @default.
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- W2170006543 doi "https://doi.org/10.1002/ejoc.201100313" @default.
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