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- W2170243490 abstract "The mechanism of pyrolysis of monosilane in the light of recent work by Robertson, Hils and Gallagher (RHG). It is argued that at reactant pressures 40 Torr, and at temperatures 650 K, the reaction is initiated homogeneously by the unimolecular process SiH4 → SiH2 + H2, as originally proposed by us, but contrary to RHG's interpretation. At low pressures, however, the reaction may well be surface initiated. In the secondary stages of decomposition we discuss possible chain branching processes involving silylenes and point out continuing mechanistic difficulties." @default.
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- W2170243490 date "1984-09-01" @default.
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- W2170243490 title "Some comments on kinetics and mechanism in the pyrolysis of monosilane" @default.
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- W2170243490 doi "https://doi.org/10.1016/0009-2614(84)85239-2" @default.
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