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- W2170260587 abstract "A number of copolysilanes, {[RR2′Si(CH2)2SiMe]x[PhR1Si]1-x}n (R, R′ = Me, Et or Ph; R1 = Me (1–3); Ph (4–6)) bearing carbosilyl side chains have been synthesized by Wurtz coupling method and characterized by GPC, multinuclear (1H, 13C{1H}, 29Si{1H}) NMR and UV spectral studies. A detailed study of 29Si{1H} NMR spectra suggests that the copolysilanes 1–3 are comprised of segregated runs of PhMeSi and RMeSi (R = carbosilyl) units while 4–6 possess many different configurational and conformational environments. The UV spectra of these copolymers reveal a distinct absorption (λmax) at 312–352 nm due to σ–σ∗ transition and show a strong dependence on the polymer composition as well as nature of the appended sila substituents." @default.
- W2170260587 created "2016-06-24" @default.
- W2170260587 creator A5031137576 @default.
- W2170260587 creator A5082571486 @default.
- W2170260587 date "2007-05-01" @default.
- W2170260587 modified "2023-09-23" @default.
- W2170260587 title "Synthesis, characterization and UV spectral studies of copolysilanes, (R, R′=Me, Et or Ph; R1=Me or Ph) bearing carbosilyl side chains" @default.
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- W2170260587 doi "https://doi.org/10.1016/j.jorganchem.2007.01.031" @default.
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