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- W2170291307 abstract "The electrochemical oxidation of the half-open complex Cp*Ru(η5-2,4-dimethyl-pentadienyl) has been carried out in acetonitrile on a glassy carbon electrode under an argon atmosphere. The monocationic complex [Cp∗Ru(CH3CN)3]+PF6- was obtained according to a one-electron mechanism involving cleavage of the pentadienyl ligand under the form of an organic radical which dimerize. In competition with this mechanism, the stable dicationic complex [Cp∗Ru(CH3CN)2(η3-2,4-dimethyl-pentadienyl)]2+(BF4-)2 was also obtained via a two-electron mechanism. The participation of the one-electron mechanism is a consequence of the slow reactivity of the RuIII species generated in the initial oxidation step of Cp*Ru(η5-2,4-dimethyl-pentadienyl)." @default.
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- W2170291307 date "2005-11-01" @default.
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- W2170291307 title "Electrochemical oxidation of Cp*Ru(η5-2,4-dimethyl-pentadienyl) in acetonitrile. One-electron vs. two-electron generation of cationic acetonitrile coordinated complexes" @default.
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- W2170291307 doi "https://doi.org/10.1016/j.jelechem.2005.07.003" @default.
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