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- W2170317726 abstract "The absorption spectra, luminescence spectra, excited-state lifetimes, and electrochemical behavior of the cyclometalated [Rh(ppz)2bpy]+, [Rh(3-Cl-ppz)2(bpy)]+, [Rh(4-NO2-ppz)2(bpy)]+, [Rh(ppz)2(biq)]+ and [Rh(4-NO2-ppz)2(biq)]+ complexes (ppz−, 3-Cl-ppz−, and 4-NO2-ppz− are the ortho-C-deprotonated forms of 1-phenylpyrazole, l-(3-chlorophenyl)pyrazole and l-(4-nitrophenyl)pyrazole, respectively) have been investigated. The results obtained have been compared with those concerning the free protonated ligands and some previously studied mixed-ligand cyclometalated Rh(III) complexes. Luminescence originates from the lowest ligand-centered (LC) excited state, which involves the diimine ligands in all cases except for [Rh(4-NO2-ppz)2(bpy)]+, where it involves the ortho-metalating ligand. s. In the absorption spectra, LC and metal-to-ligand charge-transfer (MLCT) bands, involving the diimine and/or the ortho-metalating ligands, have been assigned, and correlations between spectroscopic and electrochemical data are discussed." @default.
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- W2170317726 date "1990-08-08" @default.
- W2170317726 modified "2023-09-27" @default.
- W2170317726 title "Spectroscopical and Electrochemical Behavior of New Mixed-Ligand Cyclometalated Rh(III) Complexes" @default.
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- W2170317726 doi "https://doi.org/10.1002/hlca.19900730519" @default.
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