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- W2170327159 abstract "The double bond in the furan and thiophen ring can be induced to participate in a Claisen–Cope-type rearrangement. Furans substituted in the 2-position react more readily than those substituted in the 3-position. The 2-methyl-buta-1,3-dienyl ether of 3-furylmethanol can, however, be made to rearrange thermally, and the aldehyde thereby obtained can be converted into the corresponding alcohol, and then, by a second Claisen–Cope reaction to torreyal. The related sesquiterpenes, neotorreyol and dendrolasin and the monoterpene perillene have been synthesized." @default.
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- W2170327159 date "1970-01-01" @default.
- W2170327159 modified "2023-10-09" @default.
- W2170327159 title "Addition of a functionalized isoprene unit to an allyl alcohol. Part II. Reactions with furylmethanol and thienylmethanol and synthesis of torreyal and dendrolasin" @default.
- W2170327159 doi "https://doi.org/10.1039/j39700000220" @default.
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