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- W2170339660 abstract "Abstract The total synthesis of 1‐2‐docosanoylamino‐ O ‐(2‐ O ‐methyl‐α‐ D ‐galactopyranosyl)‐1,3,4‐octadecanetriol ( 2 ), a 2′‐methoxy analog of the immunostimulating α‐galactoglycosphingolipid 1 , is reported. Stereoselective α‐glycosylation of the azido precursor of sphingosine was successfully performed for the first time using an improved Mukaiyama reaction. When assayed in a 72 h splenocyte proliferation test, compound 2 was significantly less stimulatory than the non‐methylated compound 1 , suggesting that the galactose 2‐OH group is essential for the immunostimulatory activity of α‐Gal‐GSLs. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)" @default.
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- W2170339660 date "2004-01-19" @default.
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- W2170339660 title "Immunomodulatory α‐Galactoglycosphingolipids: Synthesis of a 2′‐<i>O</i>‐Methyl‐α‐Gal‐GSL and Evaluation of Its Immunostimulating Capacity" @default.
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