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• W2170350007 abstract "A convenient two-step homologation of both aliphatic and aromatic ketones to the corresponding carboxylic acid has been developed. First ketones were converted to epoxynitriles with the Darzens reaction. Second, a Lewis acid mediated rearrangement of these epoxynitriles with lithium bromide was achieved to give homologated secondary alkanoic acids (as well as aryl-alkanoic) in good yields. The mechanism and the scope of the rearrangement reaction were investigated. This strategy constitutes a two-step homologation of ketones to secondary carboxylic acids." @default.
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• W2170350007 date "2002-06-21" @default.
• W2170350007 modified "2023-09-27" @default.
• W2170350007 title "Rearrangement of Epoxynitriles: A Convenient Homologation of Acyclic and Cyclic Ketones to Carboxylic Acids" @default.
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• W2170350007 doi "https://doi.org/10.1021/jo025737g" @default.
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