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- W2170363003 abstract "Novel and homogeneous zirconium phosphonate-supported Pd catalysts with modest BET surface areas (25.6 and 24.7 m2 g−1), high pore volumes (0.39 and 0.73 cc g−1) and nano-sized pores (1–10 nm) were prepared by embedding Na2PdCl4 particles in an organosoluble, porous and layered zirconium phosphonate with a filiform architecture structure for the first time. In the homogeneous palladium-catalyzed Suzuki coupling reaction at room temperature, various substituted benzene bromides with phenylboronic acids were smoothly converted into corresponding biphenyl compounds (82–97% yields), even in cases of electron–rich derivatives. These supported homogeneous Pd catalysts could be quantitatively recovered by using a solid/liquid separation technique and be highly active without loss of catalytic activity in three consecutive runs." @default.
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- W2170363003 date "2012-01-01" @default.
- W2170363003 modified "2023-09-25" @default.
- W2170363003 title "Homogenization of inorganic material-supported palladium catalysts in Suzuki coupling reaction at room temperature" @default.
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- W2170363003 doi "https://doi.org/10.1039/c2cy00001f" @default.
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