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- W2170455426 abstract "The effects of adding A–B diblock copolymer to a polymer blend (A/B) on phase-separation kinetics and morphology have been investigated in a fixed shallow-quench condition (ΔT = 1.5 °C) by in situ time-resolved light scattering and phase-contrast optical microscopy. A shear-quench technique was used in this study instead of a conventional temperature-quench method. Mixtures of nearly monodisperse low relative-molecular masses of polybutadiene (Mw = 2.8 kg/mol), polystyrene (Mw = 2.6 kg/mol), and a near-symmetric butadiene–styrene diblock copolymer (Mw = 6.3 kg/mol) as an interfacial modifier were studied. We observed that the addition of the diblock copolymer could either retard or accelerate the phase-separation kinetics depending on the concentration of the diblock copolymer in the homopolymer blends. In contrast to the conventional temperature quench, we observed complex phase-separation kinetics in the intermediate and late stages of phase separation by the shear-quench technique. © 2001 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 39: 819–830, 2001" @default.
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- W2170455426 date "2001-01-01" @default.
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- W2170455426 title "Phase separation induced by shear quenching in polymer blends with a diblock copolymer" @default.
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- W2170455426 doi "https://doi.org/10.1002/polb.1056" @default.
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