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• W2170662144 abstract "The high-pressure behaviour of fibrous zeolites scolecite and thomsonite in penetrating aqueous medium was studied using in situ synchrotron powder diffraction data from diamond anvil cell. Both zeolites exhibit anomalous compressibility due to an additional pressure-induced hydration of structure channels. At 1.23 GPa, scolecite undergoes transformation to high-hydrated phase, which is expanded by 5.0% as compared to original scolecite due to the increase of zeolitic water content from 3 to 4.6 molecules per formula unit. The compressibility of thomsonite is markedly lower than that reported previously, where a nominally penetrating medium with 6% H2O was used. This indicates to an additional hydration under high pressure, which is confirmed by the observed phase transition in thomsonite. The over-hydration effect in fibrous zeolites seems to largely depend on partial water pressure in compressing medium." @default.
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• W2170662144 date "2006-12-01" @default.
• W2170662144 modified "2023-09-27" @default.
• W2170662144 title "Anomalous compression of scolecite and thomsonite in aqueous medium to 2 GPa" @default.
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• W2170662144 doi "https://doi.org/10.1080/08957950601092168" @default.
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