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- W2170685346 abstract "The pure rotational Raman spectra of 1,3,5-trifluorobenzene and hexafluorobenzene have been photographed under high resolution using a single mode argon laser as the exciting source. The observed spectra consist of sharp, highly symmetric lines which form well developed R- and S-branches. The analysis of the spectra was performed on the basis of the theory of the non-rigid, symmetric top rotor. The following ground state constants were determined. For 1,3,5-trifluorobenzene, Bo = 0.0586517 ± (5 × 10−7) cm−1 and Dj = (1.89 ± 0.04) × 10−9 cm−1; for hexafluorobenzene, Bo = 0.0343165 ± 9 × 10−7 cm−1 and Dj = (0.70 ± 0.04) × 10−9 cm−1. The CF bond lengths for these molecules were determined by assuming the values of the carbon ring parameters of benzene. The CF bond lengths (r0-values) of 1,3,5-trifluorobenzene and hexafluorobenzene are then, respectively, 1.304 Å and 1.321 Å. These values are in good agreement with the CF bond lengths determined by means of the electron diffraction technique." @default.
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- W2170685346 date "1973-04-01" @default.
- W2170685346 modified "2023-10-17" @default.
- W2170685346 title "High resolution Raman spectroscopy of gases with laser sources. VI. The rotaitional spectra of 1,3,5-trifluorobenzene and hexafluorobenzene" @default.
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- W2170685346 doi "https://doi.org/10.1002/jrs.1250010102" @default.
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