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• W2170739125 abstract "1,5-Dithiacyclooctane is shown to chemically react more efficiently and to remove singlet oxygen from solution more rapidly than either thiane or 1,4-dithiane. These unusual characteristics of the 1,5-dithiacyclooctane reaction were explored using ab initio quantum chemical methods. A large number of persulfoxides, thiadioxiranes, and hydroperoxy sulfonium ylides were located and their structures analyzed. The unusual efficiency of the reaction was attributed to a conformational change that electrostatically stabilized the persulfoxide and increased the potential energy barrier for physical quenching." @default.
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• W2170739125 date "2005-08-02" @default.
• W2170739125 modified "2023-10-18" @default.
• W2170739125 title "Conformationally Induced Electrostatic Stabilization of Persulfoxides: A New Suggestion for Inhibition of Physical Quenching of Singlet Oxygen by Remote Functional Groups" @default.
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• W2170739125 doi "https://doi.org/10.1021/ja0525509" @default.
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