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- W2170743874 abstract "Polymeric and monomeric V(V) chiral salen complexes-catalyzed enantioselective ethyl cyanoformylation of aldehydes using ethyl cyanoformate as a source of cyanide was accomplished in the presence of several basic cocatalysts viz., NaOH, KOH, basic Al2O3 and hydrotalcite. Excellent yield (>95%) of chiral ethyl cyanohydrincarbonate with high enantioselectivity up to 94% was achieved in 24–36 h when hydrotalcite was used as an additive. The polymeric catalyst 1 is more reactive than the monomeric catalyst 2 to produce chiral ethyl cyanohydrincarbonate in high optical purity. The chiral polymeric catalyst 1 and cocatalysts hydrotalcite and basic alumina used in this study were recoverable and recyclable several times with retention of its performance. Chirality, 2010. © 2009 Wiley-Liss, Inc." @default.
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- W2170743874 date "2010-01-01" @default.
- W2170743874 modified "2023-10-11" @default.
- W2170743874 title "Enantioselective cyanoformylation of aldehydes catalyzed with solid base mediated chiral V(V) salen complexes" @default.
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- W2170743874 doi "https://doi.org/10.1002/chir.20719" @default.
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