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- W2170841129 abstract "Phenylgalliumdiiodid und Methylgalliumdiiodid reagieren mit Alkyl- und Arylthiolen unter Bildung der entsprechenden Diiodalkylthio- bzw. Diiodarylthiogallane. Bei den Umsetzungen von Methylgalliumdiiodid kann das primär gebildete Addukt sowohl 1H-NMR- als auch IR-spektroskopisch nachgewiesen werden; es ist sogar möglich, einige dieser Addukte kurzzeitig in Substanz zu fassen. Die 1H-NMR-Spektren einiger Thiogallane deuten auf ein interessantes strukturelles Phänomen hin. IR-Spektren und Molmassen sind angegeben. On the Reactivity of Phenyldiiodogallane and Methyldiiodogallane with Alkyl- and Arylthiols Phenyldiiodogallane as well as methyldiiodogallane react with alkyl- as well as arylthiols under formation of the corresponding diiodoalkylthio- and diiodoarylthiogallanes. The reactions of methyldiiodogallane primary lead to the adducts, which can be characterized by 1H-n.m.r. and i.r. spectra; it is even possible to take hold of some of these adducts for a short time in substance. The 1H-n.m.r. spectra of some thiogallanes are pointing out an interesting structural phenomenon. I.r. spectra and molecular weights are reported." @default.
- W2170841129 created "2016-06-24" @default.
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- W2170841129 date "1984-07-01" @default.
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- W2170841129 title "�ber die Reaktivit�t von Phenylgalliumdiiodid und Methylgalliumdiiodid mit Alkyl- und Arylthiolen" @default.
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- W2170841129 doi "https://doi.org/10.1002/zaac.19845140724" @default.
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