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- W2170873094 abstract "A direct asymmetric substitution was developed for the reaction of cyclic Morita–Baylis–Hillman alcohols with 3-benzyl-2-oxindoles that are catalyzed by a primary amine derived from alkaloids in combination with trifluoroacetic acid. The unusual δ-products with vicinal chiral quaternary and tertiary carbon centers were obtained as the major products in yields up to 73 % with excellent diastereoselectivities (up to 99:1) and enantioselectivities (up to 98 % ee)." @default.
- W2170873094 created "2016-06-24" @default.
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- W2170873094 date "2013-02-20" @default.
- W2170873094 modified "2023-10-17" @default.
- W2170873094 title "An Organocatalytic, δ-Regioselective, Diastereoselective, and Enantioselective Nucleophilic Substitution of Cyclic Morita-Baylis-Hillman Alcohols withN-Boc-3-benzyl-2-oxindoles" @default.
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- W2170873094 doi "https://doi.org/10.1002/ejoc.201201461" @default.
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