Matches in SemOpenAlex for { <https://semopenalex.org/work/W2170895634> ?p ?o ?g. }
- W2170895634 endingPage "501" @default.
- W2170895634 startingPage "487" @default.
- W2170895634 abstract "The direct synthesis of hydrogen peroxide (H2O2) represents a potential alternative to the currently industrially used anthraquinone process, and Au–Pd catalysts have been identified as effective catalysts. To obtain a direct process, a detailed understanding of the reaction conditions in a continuous flow system is needed. In this study, we use a flow reactor to study reaction conditions independently, including total gas flow rate, catalyst mass, reaction pressure, solvent flow rate, and H2/O2 molar ratio. The study was carried out without the addition of any halide or acid additives often used to suppress the sequential hydrogenation and decomposition reactions that allowed the kinetics of these reactions to be studied along with the synthesis reaction. A global kinetic model describing the net and gross synthesis rate is proposed, and on the basis of this model, we propose that the decomposition reaction suppresses the production of H2O2 to a greater extent than hydrogenation and that catalyst design studies should aim at blocking or generating catalysts without O–O dissociation sites." @default.
- W2170895634 created "2016-06-24" @default.
- W2170895634 creator A5020068159 @default.
- W2170895634 creator A5022236235 @default.
- W2170895634 creator A5026115769 @default.
- W2170895634 creator A5044793501 @default.
- W2170895634 creator A5063392973 @default.
- W2170895634 creator A5089527779 @default.
- W2170895634 date "2013-02-21" @default.
- W2170895634 modified "2023-09-28" @default.
- W2170895634 title "Effect of Reaction Conditions on the Direct Synthesis of Hydrogen Peroxide with a AuPd/TiO<sub>2</sub> Catalyst in a Flow Reactor" @default.
- W2170895634 cites W1963782131 @default.
- W2170895634 cites W1964207692 @default.
- W2170895634 cites W1971488541 @default.
- W2170895634 cites W1972243282 @default.
- W2170895634 cites W1973599982 @default.
- W2170895634 cites W1973858361 @default.
- W2170895634 cites W1974577624 @default.
- W2170895634 cites W1974950597 @default.
- W2170895634 cites W1981951700 @default.
- W2170895634 cites W1985822500 @default.
- W2170895634 cites W1991690499 @default.
- W2170895634 cites W1995503390 @default.
- W2170895634 cites W2003286887 @default.
- W2170895634 cites W2006726351 @default.
- W2170895634 cites W2006875843 @default.
- W2170895634 cites W2016365317 @default.
- W2170895634 cites W2029557700 @default.
- W2170895634 cites W2033790566 @default.
- W2170895634 cites W2044995177 @default.
- W2170895634 cites W2047514586 @default.
- W2170895634 cites W2049170325 @default.
- W2170895634 cites W2057413542 @default.
- W2170895634 cites W2057914810 @default.
- W2170895634 cites W2063662235 @default.
- W2170895634 cites W2063889206 @default.
- W2170895634 cites W2071139981 @default.
- W2170895634 cites W2072152303 @default.
- W2170895634 cites W2075217728 @default.
- W2170895634 cites W2075227318 @default.
- W2170895634 cites W2076433029 @default.
- W2170895634 cites W2082640931 @default.
- W2170895634 cites W2083287114 @default.
- W2170895634 cites W2086083872 @default.
- W2170895634 cites W2091983166 @default.
- W2170895634 cites W2101733373 @default.
- W2170895634 cites W2110534188 @default.
- W2170895634 cites W2110559943 @default.
- W2170895634 cites W2169756802 @default.
- W2170895634 cites W2170608319 @default.
- W2170895634 cites W2313348740 @default.
- W2170895634 cites W2318767966 @default.
- W2170895634 cites W2332566260 @default.
- W2170895634 cites W2800897748 @default.
- W2170895634 cites W2950812752 @default.
- W2170895634 cites W2988019223 @default.
- W2170895634 doi "https://doi.org/10.1021/cs400004y" @default.
- W2170895634 hasPublicationYear "2013" @default.
- W2170895634 type Work @default.
- W2170895634 sameAs 2170895634 @default.
- W2170895634 citedByCount "90" @default.
- W2170895634 countsByYear W21708956342013 @default.
- W2170895634 countsByYear W21708956342014 @default.
- W2170895634 countsByYear W21708956342015 @default.
- W2170895634 countsByYear W21708956342016 @default.
- W2170895634 countsByYear W21708956342017 @default.
- W2170895634 countsByYear W21708956342018 @default.
- W2170895634 countsByYear W21708956342019 @default.
- W2170895634 countsByYear W21708956342020 @default.
- W2170895634 countsByYear W21708956342021 @default.
- W2170895634 countsByYear W21708956342022 @default.
- W2170895634 countsByYear W21708956342023 @default.
- W2170895634 crossrefType "journal-article" @default.
- W2170895634 hasAuthorship W2170895634A5020068159 @default.
- W2170895634 hasAuthorship W2170895634A5022236235 @default.
- W2170895634 hasAuthorship W2170895634A5026115769 @default.
- W2170895634 hasAuthorship W2170895634A5044793501 @default.
- W2170895634 hasAuthorship W2170895634A5063392973 @default.
- W2170895634 hasAuthorship W2170895634A5089527779 @default.
- W2170895634 hasConcept C102931765 @default.
- W2170895634 hasConcept C124681953 @default.
- W2170895634 hasConcept C127413603 @default.
- W2170895634 hasConcept C132482357 @default.
- W2170895634 hasConcept C161790260 @default.
- W2170895634 hasConcept C171560689 @default.
- W2170895634 hasConcept C175113610 @default.
- W2170895634 hasConcept C178790620 @default.
- W2170895634 hasConcept C179104552 @default.
- W2170895634 hasConcept C185592680 @default.
- W2170895634 hasConcept C2780471494 @default.
- W2170895634 hasConcept C42360764 @default.
- W2170895634 hasConcept C533411734 @default.
- W2170895634 hasConceptScore W2170895634C102931765 @default.
- W2170895634 hasConceptScore W2170895634C124681953 @default.
- W2170895634 hasConceptScore W2170895634C127413603 @default.
- W2170895634 hasConceptScore W2170895634C132482357 @default.
- W2170895634 hasConceptScore W2170895634C161790260 @default.
- W2170895634 hasConceptScore W2170895634C171560689 @default.