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• W2170918744 abstract "The reaction of (CpCrSCMe3)2S and the adducts (CpCrSCMe3)2S·ML (ML = Cr(CO)5, Mn2(CO)9 and cluster (CpCrS)2(SCMe3)·Fe(CO)3 (I) (containing CrCrFe metal chain) with benzoic acid gives the respective antiferromagnetic μ3-thio-bridged carboxylates Cr2MS(OOCPh)6 (M = Cr(II), Mn(II), Fe(II)) (II–IV). On the other hand the reaction of I with the weaker trimethylacetic acid yields the tetrahedral cluster Cp3Cr3(μ3-S)4Fe(OOCCMe3) (V) containing two unpaired electrons (μeff = 2.81 BM). Crystal structure of V was solved by means of X-ray analysis (sp. gr. C2)c, a = 28.905(2), b = 9.563(2), c = 23.789(2) Å, β = 131.84(3)°, V = 4902.8(4) Å3 Z = 4). In the metal tetrahedral skeleton Cr3Fe the average bond lengths CrCr and FeCr are 2.838(3) and 2.759(3) Å respectively. The μ3-bridged sulfur atom locates over each tetrahedron face (the average CrS and FeS distances are 2.258(4) and 2.218(4) Å respectively). Each chromium atom is combined to η5-C5H5 ligand (the average CrC and CC distances are 2.224(20) and 1.391(30) Å). The iron atom is bound to a terminal trimethylacetate group (FeO 1.896(10), O(1)C(1) 1.318(13), O(2)C(1) 1.252(21) Å)." @default.
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• W2170918744 date "1983-01-01" @default.
• W2170918744 modified "2023-10-18" @default.
• W2170918744 title "Interaction of Heteronuclear chromium-containing clusters with carboxalic acids. Molecular structure of the paramagnetic tetrahedral cluster Cp3Cr3(μ3-S)4Fe(OOCCMe3)" @default.
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• W2170918744 doi "https://doi.org/10.1016/s0020-1693(00)90855-7" @default.
• W2170918744 hasPublicationYear "1983" @default.
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