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• W2171015890 abstract "The reactivity of different α-hematite (α-Fe2O3) systems for dechlorination of trichloroethylene (TCE) in the presence of Fe(II) and CaO was investigated. Initially different experiments were conducted to investigate the reactivity of pure and doped α-Fe2O3. It was found that the presence of elements such as Si, Cu, and Mn in α-Fe2O3 had a significant effect on TCE reduction potential of α-Fe2O3; however, the reduction potential was less than that of α-Fe2O3 (Bayferrox®-110 M, used in a previous study). Further studies were carried out and α-Fe2O3 was synthesized in a manner similar to that of Bayferrox®-110 M. This synthetic α-Fe2O3 showed improved reactivity and was found to follow pseudo-first-order kinetics when used in TCE reduction experiments. The preliminary end products analysis showed that TCE degradation was probably via β-elimination pathway. Detailed investigations of α-Fe2O3 systems were carried out using X-ray diffraction, X-ray fluorescence, and scanning electron microscopy with energy-dispersive spectrometry. The results demonstrated that the TCE reduction capacity of α-Fe2O3 was strongly dependent on the other elements present in iron powder used to synthesize α-Fe2O3. It was suspected that these multi-elements in α-Fe2O3 helped to improve its conduction property. Current findings suggest that α-Fe2O3 not in the pure but combined with other elements could be thought as a potential system for TCE reduction." @default.
• W2171015890 created "2016-06-24" @default.
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• W2171015890 date "2013-06-07" @default.
• W2171015890 modified "2023-09-25" @default.
• W2171015890 title "New and effective multi-element α-hematite systems for reduction of trichloroethylene" @default.
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• W2171015890 doi "https://doi.org/10.1080/09593330.2013.805819" @default.
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