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• W2171233561 abstract "In the present work, the (K(0.5x)Bi(1-0.5x))(Mo(x)V(1-x))O(4) ceramics (0≤x ≤ 1.00) were prepared via the solid state reaction method and sintered at temperatures below 830 °C. At room temperature, the BiVO(4) scheelite monoclinic solid solution was formed in ceramic samples with x < 0.10. When x lies between 0.1-0.19, a BiVO(4) scheelite tetragonal phase was formed. The phase transition from scheelite monoclinic to scheelite tetragonal phase is a continuous, second order ferroelastic transition. High temperature X-ray diffraction results showed that this phase transition can also be induced at high temperatures about 62 °C for x = 0.09 sample, and has a monoclinic phase at room temperature. Two scheelite tetragonal phases, one being a BiVO(4) type and the other phase is a (K,Bi)(1/2)MoO(4) type, coexist in the compositional range 0.19 < x < 0.82. A pure (K,Bi)(1/2)MoO(4) tetragonal type solid solution can be obtained in the range 0.82 ≤ x ≤ 0.85. Between 0.88 ≤ x ≤ 1.0, a (K,Bi)(1/2)MoO(4) monoclinic solid solution region was observed. Excellent microwave dielectric performance with a relative dielectric permittivity around 78 and Qf value above 7800 GHz were achieved in ceramic samples near the ferroelastic phase boundary (at x = 0.09 and 0.10)." @default.
• W2171233561 created "2016-06-24" @default.
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• W2171233561 date "2011-11-21" @default.
• W2171233561 modified "2023-10-16" @default.
• W2171233561 title "Phase Evolution, Phase Transition, Raman Spectra, Infrared Spectra, and Microwave Dielectric Properties of Low Temperature Firing (K_0.5<i>x</i>Bi_{1–0.5<i>x</i>})(Mo_<i>x</i>V_1–<i>x</i>)O₄ Ceramics with Scheelite Related Structure" @default.
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• W2171233561 doi "https://doi.org/10.1021/ic201862e" @default.
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