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• W2171387881 startingPage "15086" @default.
• W2171387881 abstract "Two 3D heterometal-organic frameworks based on infrequent trigonal bipyramidal Ln(5) clusters as nodes were structurally and magnetically characterized (Ln=Gd (1), Dy (2)). The results indicate large MCE of up to 30.7 J kg(-1) K(-1) in 1 and slow magnetic relaxation behavior in 2. Expectedly, constructing 3D MOFs based on multinuclear clusters as nodes may will be a new strategy for achieving large -ΔS(m). Additionally, compound 1 exhibits high thermal and solvent stabilities, providing a favorable foundation for realistic applications." @default.
• W2171387881 created "2016-06-24" @default.
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• W2171387881 date "2012-10-18" @default.
• W2171387881 modified "2023-10-18" @default.
• W2171387881 title "3 D MOFs Containing Trigonal Bipyramidal Ln₅ Clusters as Nodes: Large Magnetocaloric Effect and Slow Magnetic Relaxation Behavior" @default.
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• W2171387881 doi "https://doi.org/10.1002/chem.201202412" @default.
• W2171387881 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23080423" @default.
• W2171387881 hasPublicationYear "2012" @default.
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