FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2171410720> ?p ?o ?g. }

• W2171410720 endingPage "2104" @default.
• W2171410720 startingPage "2101" @default.
• W2171410720 abstract "P,N-ligands trans-4 and cis-5 with a cyclohexane backbone were easily synthesized. The key step was chiral resolution of (±)-trans-2-pyridylcyclohexanols with DBTA. Enantiopure trans isomer was subjected to Mitsunobu reaction and deprotection to give the corresponding cis isomer. These ligands have been successfully used in asymmetric hydrogenation of arylalkenes with up to 93% ee using 5 and 90% ee using 4 and asymmetric allylic alkylations with up to 95% ee using 5 and 93% ee using 4. Trans and cis P,N-ligands 4 and 5 all gave the product with the same configuration. It was suggested that the absolute configuration of the product was controlled by the configuration of the stereogenic pyridyl-bearing carbon of the ligands." @default.
• W2171410720 created "2016-06-24" @default.
• W2171410720 creator A5015288133 @default.
• W2171410720 creator A5073407872 @default.
• W2171410720 date "2007-03-01" @default.
• W2171410720 modified "2023-10-17" @default.
• W2171410720 title "Synthesis of chiral cyclohexane-backbone P,N-ligands derived from pyridine and their applications in asymmetric catalysis" @default.
• W2171410720 cites W1966137197 @default.
• W2171410720 cites W1967908946 @default.
• W2171410720 cites W1972874786 @default.
• W2171410720 cites W1979640190 @default.
• W2171410720 cites W1986647122 @default.
• W2171410720 cites W1992250684 @default.
• W2171410720 cites W1994417769 @default.
• W2171410720 cites W2026805595 @default.
• W2171410720 cites W2033396614 @default.
• W2171410720 cites W2044293807 @default.
• W2171410720 cites W2046150172 @default.
• W2171410720 cites W2048727748 @default.
• W2171410720 cites W2053551622 @default.
• W2171410720 cites W2056717953 @default.
• W2171410720 cites W2065787698 @default.
• W2171410720 cites W2084311233 @default.
• W2171410720 cites W2101826827 @default.
• W2171410720 cites W2105299237 @default.
• W2171410720 cites W2117337488 @default.
• W2171410720 cites W2117487885 @default.
• W2171410720 cites W2141711828 @default.
• W2171410720 cites W2152156658 @default.
• W2171410720 cites W2153624834 @default.
• W2171410720 cites W2161382456 @default.
• W2171410720 cites W2168859204 @default.
• W2171410720 cites W2949616433 @default.
• W2171410720 cites W2949945402 @default.
• W2171410720 cites W2950074726 @default.
• W2171410720 cites W2950255970 @default.
• W2171410720 cites W2952332794 @default.
• W2171410720 cites W4246653786 @default.
• W2171410720 cites W4376849162 @default.
• W2171410720 doi "https://doi.org/10.1016/j.tetlet.2007.01.123" @default.
• W2171410720 hasPublicationYear "2007" @default.
• W2171410720 type Work @default.
• W2171410720 sameAs 2171410720 @default.
• W2171410720 citedByCount "22" @default.
• W2171410720 countsByYear W21714107202012 @default.
• W2171410720 countsByYear W21714107202013 @default.
• W2171410720 countsByYear W21714107202015 @default.
• W2171410720 countsByYear W21714107202016 @default.
• W2171410720 countsByYear W21714107202018 @default.
• W2171410720 countsByYear W21714107202019 @default.
• W2171410720 countsByYear W21714107202020 @default.
• W2171410720 countsByYear W21714107202022 @default.
• W2171410720 countsByYear W21714107202023 @default.
• W2171410720 crossrefType "journal-article" @default.
• W2171410720 hasAuthorship W2171410720A5015288133 @default.
• W2171410720 hasAuthorship W2171410720A5073407872 @default.
• W2171410720 hasConcept C116569031 @default.
• W2171410720 hasConcept C120095180 @default.
• W2171410720 hasConcept C134195300 @default.
• W2171410720 hasConcept C146686406 @default.
• W2171410720 hasConcept C155647269 @default.
• W2171410720 hasConcept C161790260 @default.
• W2171410720 hasConcept C170493617 @default.
• W2171410720 hasConcept C176788430 @default.
• W2171410720 hasConcept C178790620 @default.
• W2171410720 hasConcept C185592680 @default.
• W2171410720 hasConcept C197356162 @default.
• W2171410720 hasConcept C25170562 @default.
• W2171410720 hasConcept C2778237882 @default.
• W2171410720 hasConcept C2779485729 @default.
• W2171410720 hasConcept C3019471444 @default.
• W2171410720 hasConcept C32489680 @default.
• W2171410720 hasConcept C45803636 @default.
• W2171410720 hasConcept C55493867 @default.
• W2171410720 hasConcept C71240020 @default.
• W2171410720 hasConcept C93237805 @default.
• W2171410720 hasConcept C95081189 @default.
• W2171410720 hasConceptScore W2171410720C116569031 @default.
• W2171410720 hasConceptScore W2171410720C120095180 @default.
• W2171410720 hasConceptScore W2171410720C134195300 @default.
• W2171410720 hasConceptScore W2171410720C146686406 @default.
• W2171410720 hasConceptScore W2171410720C155647269 @default.
• W2171410720 hasConceptScore W2171410720C161790260 @default.
• W2171410720 hasConceptScore W2171410720C170493617 @default.
• W2171410720 hasConceptScore W2171410720C176788430 @default.
• W2171410720 hasConceptScore W2171410720C178790620 @default.
• W2171410720 hasConceptScore W2171410720C185592680 @default.
• W2171410720 hasConceptScore W2171410720C197356162 @default.
• W2171410720 hasConceptScore W2171410720C25170562 @default.
• W2171410720 hasConceptScore W2171410720C2778237882 @default.
• W2171410720 hasConceptScore W2171410720C2779485729 @default.
• W2171410720 hasConceptScore W2171410720C3019471444 @default.
• W2171410720 hasConceptScore W2171410720C32489680 @default.
• W2171410720 hasConceptScore W2171410720C45803636 @default.
• W2171410720 hasConceptScore W2171410720C55493867 @default.
• W2171410720 hasConceptScore W2171410720C71240020 @default.
• W2171410720 hasConceptScore W2171410720C93237805 @default.
• W2171410720 hasConceptScore W2171410720C95081189 @default.

• next