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- W2171569470 abstract "We perform a systematic investigation of the resonance and vibrational properties of naphthyl-terminated sp carbon chains (dinaphthylpolyynes) by combined multi-wavelength resonant Raman (MWRR) spectroscopy, ultraviolet-visible spectroscopy, and Fourier-transform infrared (FT-IR) spectroscopy, plus ab initio density functional theory (DFT) calculations. We show that the MWWR and FT-IR spectroscopies are particularly suited to identify chains of different lengths and different terminations, respectively. By DFT calculations, we further extend those findings to sp carbon chains end-capped by other organic structures. The present analysis shows that combined MWRR and FT-IR provide a powerful tool to draw a complete picture of chemically stabilized sp carbon chains." @default.
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- W2171569470 date "2011-11-17" @default.
- W2171569470 modified "2023-09-28" @default.
- W2171569470 title "Vibrational characterization of dinaphthylpolyynes: A model system for the study of end-capped <i>sp</i> carbon chains" @default.
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- W2171569470 doi "https://doi.org/10.1063/1.3660211" @default.
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