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- W2171582009 abstract "Reaction of the lithium salts of N,N′-dialkyl-2-amino-4-imino-pent-2-enes, nacnacRLi(THF) (R = CH2Ph, Cy, nPr, iBu or S–CH(Me)Ph), with half an equivalent of CrCl2(THF)x yielded the homoleptic complexes (nacnacR)2Cr. All complexes were characterized by X-ray diffraction studies and displayed a highly symmetric, square-planar coordination around the chromium center with strong boat-like distortions of the diketiminate ligands. Reaction of nacnacRLi(THF) (R = CH2Ph, Cy) with one equivalent of CrCl2(THF)x afforded the dimeric complexes {nacnacRCr(μ-Cl)}2." @default.
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- W2171582009 date "2011-01-01" @default.
- W2171582009 modified "2023-10-03" @default.
- W2171582009 title "Highly symmetrical chromium(II) bisdiketiminate complexes" @default.
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- W2171582009 doi "https://doi.org/10.1016/j.ica.2010.08.005" @default.
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