Matches in SemOpenAlex for { <https://semopenalex.org/work/W2171590389> ?p ?o ?g. }
Showing items 1 to 78 of
78
with 100 items per page.
- W2171590389 endingPage "400" @default.
- W2171590389 startingPage "398" @default.
- W2171590389 abstract "Methyl esters of undecenoic, oleic, erucic, linoleic, gorlic, ricinoleic, 12-hydroxystearic, 9,10-dihydroxystearic, 12-ketostearic and 9,10-epoxystearic acids were reduced to alcohols by refluxing with sodium borohydride in t-butanol-methanol. The products were found by chromatographic and spectral techniques to consist of mainly alcohols and small quantities of unreduced esters. Methyl undecenoate and gorlate also yielded minor proportions of corresponding wax esters. Olefinic unsaturation was not affected. Keto and epoxy groups were reduced faster than ester groups, hydroxy esters faster than nonhydroxy esters and shorter-chain esters faster than longer-chain esters. Reduktion von Fettsäuremethylestern mit Natriumborhydrid-t-Butanol-Methanol Es wurden die Methylester von Undecensäure, Ölsäure, Erucasäure, Linolsäure, Gorlisäure, Rizinolsäure, 12-Hydroxystearinsäure, 9,10-Dihydroxystearinsäure, 12-Ketostearinsäure und 9,10-Epoxistearinsäure durch Kochen am Rückflußkühler mit Natriumborhydrid in t-Butanol-Methanol zu den Alkoholen reduziert. Durch Chromatographie und Spektraltechniken wurde gefunden, daß diese Produkte hauptsächlich aus Alkoholen und kleinen Mengen unreduzierter Ester bestehen. Die Methylester der Undecensäure und Gorlisäure bildeten ebenfalls kleinere Mengen der entsprechenden Wachsester. Die olefinische Doppelbindung blieb unberührt. Keto- und Epoxigruppen wurden schneller als Estergruppen reduziert, Hydroxiester schneller als Nichthydroxiester und kurzkettige Ester schneller als langkettige." @default.
- W2171590389 created "2016-06-24" @default.
- W2171590389 creator A5044583865 @default.
- W2171590389 creator A5046296932 @default.
- W2171590389 creator A5086886723 @default.
- W2171590389 date "1987-01-01" @default.
- W2171590389 modified "2023-10-13" @default.
- W2171590389 title "Reduction of Fatty Acid Methyl Esters with Sodium Borohydride‐t‐Butanol‐Methanol" @default.
- W2171590389 cites W1966555462 @default.
- W2171590389 cites W2002326424 @default.
- W2171590389 cites W2007302177 @default.
- W2171590389 cites W2016808316 @default.
- W2171590389 cites W2019136377 @default.
- W2171590389 cites W2028875119 @default.
- W2171590389 cites W2043352072 @default.
- W2171590389 cites W2061755977 @default.
- W2171590389 cites W2062548123 @default.
- W2171590389 cites W2070981278 @default.
- W2171590389 cites W2086692556 @default.
- W2171590389 cites W2313482997 @default.
- W2171590389 cites W2318671987 @default.
- W2171590389 cites W2321957316 @default.
- W2171590389 cites W2332355733 @default.
- W2171590389 cites W2335675279 @default.
- W2171590389 cites W2415799111 @default.
- W2171590389 doi "https://doi.org/10.1002/lipi.19870891006" @default.
- W2171590389 hasPublicationYear "1987" @default.
- W2171590389 type Work @default.
- W2171590389 sameAs 2171590389 @default.
- W2171590389 citedByCount "1" @default.
- W2171590389 countsByYear W21715903892023 @default.
- W2171590389 crossrefType "journal-article" @default.
- W2171590389 hasAuthorship W2171590389A5044583865 @default.
- W2171590389 hasAuthorship W2171590389A5046296932 @default.
- W2171590389 hasAuthorship W2171590389A5086886723 @default.
- W2171590389 hasConcept C155647269 @default.
- W2171590389 hasConcept C161790260 @default.
- W2171590389 hasConcept C178790620 @default.
- W2171590389 hasConcept C185592680 @default.
- W2171590389 hasConcept C201268389 @default.
- W2171590389 hasConcept C2779607525 @default.
- W2171590389 hasConcept C2780048404 @default.
- W2171590389 hasConcept C2780809830 @default.
- W2171590389 hasConcept C2781403372 @default.
- W2171590389 hasConcept C543025807 @default.
- W2171590389 hasConcept C55493867 @default.
- W2171590389 hasConceptScore W2171590389C155647269 @default.
- W2171590389 hasConceptScore W2171590389C161790260 @default.
- W2171590389 hasConceptScore W2171590389C178790620 @default.
- W2171590389 hasConceptScore W2171590389C185592680 @default.
- W2171590389 hasConceptScore W2171590389C201268389 @default.
- W2171590389 hasConceptScore W2171590389C2779607525 @default.
- W2171590389 hasConceptScore W2171590389C2780048404 @default.
- W2171590389 hasConceptScore W2171590389C2780809830 @default.
- W2171590389 hasConceptScore W2171590389C2781403372 @default.
- W2171590389 hasConceptScore W2171590389C543025807 @default.
- W2171590389 hasConceptScore W2171590389C55493867 @default.
- W2171590389 hasIssue "10" @default.
- W2171590389 hasLocation W21715903891 @default.
- W2171590389 hasOpenAccess W2171590389 @default.
- W2171590389 hasPrimaryLocation W21715903891 @default.
- W2171590389 hasRelatedWork W1592823107 @default.
- W2171590389 hasRelatedWork W1965978602 @default.
- W2171590389 hasRelatedWork W1985541958 @default.
- W2171590389 hasRelatedWork W2017605923 @default.
- W2171590389 hasRelatedWork W2353254367 @default.
- W2171590389 hasRelatedWork W2357059843 @default.
- W2171590389 hasRelatedWork W2367116563 @default.
- W2171590389 hasRelatedWork W2386160135 @default.
- W2171590389 hasRelatedWork W3034512975 @default.
- W2171590389 hasRelatedWork W4308867602 @default.
- W2171590389 hasVolume "89" @default.
- W2171590389 isParatext "false" @default.
- W2171590389 isRetracted "false" @default.
- W2171590389 magId "2171590389" @default.
- W2171590389 workType "article" @default.