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- W2171648864 abstract "α,β-Unsaturated aldehydes are prepared from easily available propargyl amides through a two-step sequence of silylformylation–desilylation reactions. The substituent on the nitrogen atom markedly influences both reactions, β-silylalkenals being formed in the presence of tosyl or tert-butoxycarbonyl protected amines. TBAF is employed to induce the desilylation process that is performed under very mild experimental conditions. A contemporary elimination step occurs when tosylamido aldehydes are reacted affording 2-methylaryl-2-alkenals, while this process can be suppressed changing the functional group to NBOC, thus allowing the formation of β-amino carbonyl compounds." @default.
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- W2171648864 date "2006-01-01" @default.
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- W2171648864 title "Silylformylation–desilylation of propargyl amides: synthesis of α,β-unsaturated aldehydes" @default.
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- W2171648864 doi "https://doi.org/10.1016/j.tetlet.2005.11.054" @default.
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