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• W2171701919 abstract "A new complex, [Ni2(H2O)(5-Br-ip)2(dps)2]n (1) (5-Br-H2ip = 5-bromoisophthalate, dps = 4,4′-dipyridylsulfide) has been hydrothermally synthesized by in situ generation of 4,4′-dipyridylsulfide ligand from a 4,4′-dipyridyldisulfide (dpds) precursor and characterized by elemental analysis, IR spectroscopy, and single-crystal X-ray analysis. Complex 1 belongs to the orthorhombic system, Fdd2 space group, a = 28.789(16) Å, b = 13.903(8) Å, c = 27.693(15) Å, F (000) = 3984, R1 = 0.0799, wR2 = 0.1957. Complex 1 contains [Ni2(H2O)]4+ dimers bridged by pairs of ligands into a single 3D diamond network with alternately left-handed and right-handed helical channels. Moreover, the thermal stabilities of 1 were also discussed. Supplemental materials are available for this article. Go to the publisher's online edition of Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry to view the supplemental file." @default.
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• W2171701919 date "2013-04-04" @default.
• W2171701919 modified "2023-09-28" @default.
• W2171701919 title "Synthesis and Crystal Structure of a Porous Framework Obtained by In Situ Ligand Formation From 4,4′-Dipyridyldisulfide" @default.
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• W2171701919 doi "https://doi.org/10.1080/15533174.2012.750349" @default.
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