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- W2171722152 abstract "Equilibrium constants were measured for the reactions of a capped zinc porphyrin with 1-methylimidazole (mim) and of metal imidazolate complexes of CuII and NiII and for zinc 5,10,15,20-tetra (o-methoxyphenyl)porphyrinole with mim in toluene at 20, 25, 30, and 35 °C. Enthalpy and entropy values obtained from a least-squares fit of a plot of In K vs. 1/T indicate that the effect of the capping benzene on the thermodynamics of the axial ligation reaction is entropic rather than enthalpic. Monoadducts of iron(III) porphyrins can be prepared using the sterically hindered ‘capped’ porphyrin. The axial adduct with the copper(II) imidazolate complex has the same binuclear core, FeIIICuII, as the resting form of the mammalian enzyme cytochrome c oxidase." @default.
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- W2171722152 date "1990-01-01" @default.
- W2171722152 modified "2023-09-27" @default.
- W2171722152 title "Steric effects in the reactions of zinc(II) and iron(III)‘capped’ porphyrins" @default.
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- W2171722152 doi "https://doi.org/10.1039/dt9900000843" @default.
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