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- W2171738893 abstract "Combination of a receptor unit with a rigid shaping unit produces a new type of receptor molecules of the cryptand class, hollow macropolycyclic molecules termed speleands, capable of substrate inclusion. Two members of this category of compounds 1 and 2, have been synthesized by connecting in a single step, a macro-cyclic [18]-N3O3 binding unit with a rigid cyclotriveratrylene unit via three bridges. Compound 1 binds the rnethylammonium cation forming both external and internal complexes; for the latter a ‘speleme’ structure, schematically represented by 15, may be proposed." @default.
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- W2171738893 date "1982-09-22" @default.
- W2171738893 modified "2023-10-16" @default.
- W2171738893 title "Speleands. Macropolycyclic receptor cages based on binding and shaping sub-units. Synthesis and properties of macrocycle cyclotriveratrylene combinations. Preliminary communication" @default.
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- W2171738893 doi "https://doi.org/10.1002/hlca.19820650623" @default.
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