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- W2171804889 abstract "Four samarium thiostannates, [Sm2(en)6(μ 2-OH)2]Sn2S6 (1), [Sm(dien)3]2[(Sn2S6)Cl2] (2a), [Sm(dien)3]2[(Sn2S6)(SH)2] (2b), and [Sm(trien)(tren)(Cl)]2Sn2S6 · en (3) (en = ethylenediamine, dien = diethylenetriamine, trien = triethylenetetraamine, tren = tris(2-aminoethyl)amine), were solvothermally synthesized and characterized. Compounds 1–3 consist of the hexathiostannate anion [Sn2S6]4− and Sm(III) complex cations. In addition, 2a and 2b contain monovalent anions Cl− and SH−, respectively. In 1, the Sm(III) ion forms a binuclear complex [Sm2(en)6(μ 2-OH)2]4+, in which Sm(III) is eight coordinate. In 2a, 2b, and 3, Sm(III) ions form mononuclear nine-coordinate complexes. The coordination modes of Sm(III) are influenced by the denticity of ethylene polyamines, and the monovalent OH− and Cl− as well. The complex [Sm(trien)(tren)(Cl)]2+ in 3 is the first example of a lanthanide complex with mixed ethylene polyamine ligands. The optical properties of 1–3 were measured." @default.
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- W2171804889 date "2010-04-29" @default.
- W2171804889 modified "2023-10-15" @default.
- W2171804889 title "Solvothermal syntheses and optical properties of hexathiostannates containing samarium(III) complexes with different ethylene polyamines" @default.
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- W2171804889 doi "https://doi.org/10.1080/00958972.2010.482666" @default.
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